User contributions for Copyplane5
13 September 2024
- 02:2502:25, 13 September 2024 diff hist +4,557 N The Advantage Of Having A Polymer Nanolayer On CNTs Widens The Ambit For Functionalizing It In Various Ways For Polymer Electronic Devices Photoresist Created page with "However , in this paper , we show for the first time experimentally that , due to a insubordinate polymer level suffer carbon nanoparticle inclusions and polymerise C nanotubes , an interesting dynamics can be work . We outset show analytically that the relative change in the immunity of a single isolated semiconductive nanotube is directly proportional to the axial and torsional dynamic strains , when the stress are little , whereas , in polymerise CNTs , the viscoelast..." current
11 September 2024
- 03:0403:04, 11 September 2024 diff hist +4,390 N Activity Cloth Response Dynamics Degradation Methyl Orange Illume Inspection systems Created page with "Their stability was investigated by reusability quiz , photoluminescence measuring , and the recharacterization after debasement . The upshot of as-deposited Ag nanoparticles was also spotlight on the photostability and the reusability of Ag ( 3 ) PO ( 4 ) . Although [https://postheaven.net/arrowberry9/for-a-rough-theoretical-approach-a-computer-simulation-is-developed-to Seebio Photolyzable Acid Precursor] deposited Ag nanoparticles suppressed the establishment of pickl..." current
10 September 2024
- 03:0903:09, 10 September 2024 diff hist +4,477 N Zno Zno Azo Zno Gzo Semiconductor Films Glass Substratum Sue Application Ultraviolet Detector KrF excimer laser photoresist Created page with "[https://postheaven.net/arrowberry9/membrane-detector-have-been-widely-used-in-various-fields-outstanding-to Mechanistic Studies of 6-butyl-n-hydroxynaphthimide trifluoromethanesulfonic acid Reactions] doping denseness of Al and Ga were 1 at % in the precursor solutions . In this learn , the microstructural features and the optical and electric properties of sol-gel-derived ZnO , AZO , and GZO thin flick were compared , and the functioning of ZnO-based UV photodetectors..." current
6 September 2024
- 03:2403:24, 6 September 2024 diff hist +4,666 N The En Splitting Tween The Promising And Dark Exciton Is Metrical By Photoluminescence Spectroscopy Nanoimprint Lithography NIL Created page with "We prove that Δ can be tuned by a few meV as a result of a significant Lamb sack of the optically active exciton that arises from emanation and absorption of virtual photons activate by the vacuum-clean fluctuations of the electromagnetic battleground . [https://kirkegaard-bang.federatedjournals.com/we-evidence-the-univocal-entangling-operation-of-a-photonic-quantum-logic-gate-labour-by-an-ultrabright-solid-state-single-photon-reference-negative-tone-photoresist 6-butyl..." current
3 September 2024
- 03:1403:14, 3 September 2024 diff hist +4,427 N Heating Device Made From 1G D1G 298 At 413 K Significantly Increases The Electrical Conduction From 6 10 4 S Cm 1 For D1G 298 To 1 10 3 S Cm 1 For D1G 413 Showing Important Quartz Form Addiction Positive Photoresist Created page with "Heat-treating D-1-G and D-1-R gimmick at unlike temperatures clearly reveal the reason for the conductivity tune . Thus , the conduction of NiL ( 2 ) -based devices could be well tuned done lechatelierite shift by heat or by soaking in solution . Theoretical calculations intelligibly revealed the reason for such conductivity changes and also predicted that both polymorphs arod p-type semiconductors with hole mobilities of 1 × 10 ( -2 ) ( 1-G ) and 2 × 10 ( -1 ) cm ( 2..." current
2 September 2024
- 02:4102:41, 2 September 2024 diff hist +4,564 N Interrelate Ideas Could Inspire The Design And Synthesis Of Hereafter Nanocomposite PhCs Photolithography process Created page with "[ Broad-area vertical cavum semiconductor ocular amplifiers ] .Based on the broad-area upright cavity semiconductor optical amplifiers ( VCSOA ) of 970 nm , the amplifier gain and bandwidth feature were experimentally enquire and analyzed in the musing mode . For 970 nm broad-area VCSOA function in broody mode , the utmost gain amplification of 24 dB and optic bandwidth of 0 nm ( 25 GHz ) were achieve when the injectant current was 57 % of doorsill stream and the signal..." current
29 August 2024
- 02:4002:40, 29 August 2024 diff hist +4,501 N Result Grandness Theat Time Spectrometry Realization Growth Semiconductor Materials Positive Photoresist Created page with "Ag-CuO-ZnO metal-semiconductor multiconcentric nanotubes for achieving superscript and durable photodegradation.Solar en represents a full-bodied and cancel form of resourcefulness for environment redress via photocatalytic pollutant degradation with minimal associated costs . yet , due to the complexity of the photodegradation process , it has been a long-standing chall to develop reliable photocatalytic organization with low recombination rates , first-class recyclabil..." current
22 August 2024
- 09:0209:02, 22 August 2024 diff hist +4,543 N Oral Bioavailability And Pharmacokinetics Of PAT5A A New Insulin Sensitizer In Rats Deep ultraviolet lithography Created page with "pharmacokinetics of PAT-5A ( a new thiazolidinedione derivative ) , a potent insulin sensitise and lipid-lowering compound was studied in rats . A single dose of 3 , 10 , 30 and 100 mg/kg PAT-5A was generate orally to Wistar rats for enquire the dose linearity in pharmacokinetics . In another survey , a single intravenous bolus dose of PAT-5A was given to rats at 10 mg/kg dose watch administration through the tail vein in orderliness to incur the absolute oral bioavailab..." current
21 August 2024
- 07:0307:03, 21 August 2024 diff hist +4,624 N NearIR Phosphorescent Metalloporphyrin As A Photochemical Upconversion Sensitiser KrF Photoresist Created page with "The phosphorescent metalloporphyrin sensitiser PtTPTNP ( TPTNP = tetraphenyltetranaphtho [ 2,3 ] porphyrin ) has been successfully coupled with perylenediimide ( PDI ) or rubrene utilized as triplet acceptors/annihilators to upconvert 690 nm incident photons into yellow fluorescence through sensitized triplet-triplet annihilation at overall efficiencies in the 6-7 % range while exhibiting olympian photostability.Microsphere photolithography with dynamic angulate spectra..." current
20 August 2024
- 03:1303:13, 20 August 2024 diff hist +4,253 N An Organocatalytic Response Was Achieved When Employing A Chiral HydrogenBonding Guide With An Confiscate Sensify Unit Benzophenone Or Xanthone Negative Photoresist Created page with "The xanthone-based organocatalyst proved to be superordinate as liken to the several benzophenone . close inspection discover that the response of 4- ( pent-4-enyloxy ) quinolone leave to a six-membered ring , annelated to the cyclobutane , was less enantioselective ( up to 41 % ee with 30 mol % catalyst ) than the response of 4- ( but-3-enyloxy ) quinolone guide to a five-membered ring ( 90 % ee with 5 mol % and 94 % ee with 20 mol % catalyst ) . Photophysical data ( em..." current
19 August 2024
- 03:5903:59, 19 August 2024 diff hist +4,236 N Knowl Study Attempt Date Impacts Heteroions Activators Sensitizers Processes Investigation Ucl Diligence Optical proximity correction methods Created page with "The two isomers of a cyclometallated palladium sensitizer show different photodynamic properties in cancer cells.This story demonstrates that switch the place of the carbon-metal bond in a polypyridyl cyclopalladated composite , going from PdL1 ( N^N^C^N ) to PdL2 ( N^N^N^C ) , dramatically work the photodynamic place of the composite in cancer cells . This issue is principally impute to the importantly difference in absorbance and singlet oxygen quantum fruit betwixt th..." current
14 August 2024
- 03:4703:47, 14 August 2024 diff hist +4,537 N Oral Bioavailability And Pharmacokinetics Of PAT5A A New Insulin Sensitiser In Rats Deep ultraviolet lithography Created page with "pharmacokinetics of PAT-5A ( a new thiazolidinedione differential ) , a potent insulin sensitise and lipid-lowering deepen was studied in rats . A single dose of 3 , 10 , 30 and 100 mg/kg PAT-5A was given orally to Wistar rats for investigating the dose one-dimensionality in pharmacokinetics . In another study , a single intravenous bolus dose of PAT-5A was given to rats at 10 mg/kg dose watch administration done the tail vein in orderliness to obtain the absolute oral b..." current
8 August 2024
- 09:4809:48, 8 August 2024 diff hist +5,297 N Clay catalysts were incorporated to further improve the products quality Created page with "The mass yield of monocyclic aromatic hydrocarbons (MAHs) increased under the catalysis of composite catalysts AZM and NiMo/AZM. HAP&Zeolite dual catalyst system reduced coke yield of NiMo/AZM to 51 wt%. Through real-time monitoring of gas products, the catalytic performance of zeolites began to decrease after the ratio of biomass and catalyst was more than 1. A series of characterization results futher demonstrated that AZM and NiMo/AZM possessed more stable catal..." current
6 August 2024
- 03:1903:19, 6 August 2024 diff hist +5,836 N These monolayers have measurable polar order Created page with "For molecules that self-associate well, the opposite orientation is observed. These films are comprised of isolated stacks of molecules parallel to the Synthesis of low-generation, aryl-/alkyl-type, nonpolar dendrons carrying protected hydroxyalkyl groups in the periphery.An efficient convergent synthesis of first- and second-generation aryl-/alkyl-type nonpolar dendrons via Suzuki cross-coupling is described. The dendrons carry either one or two benzyl-protected hydroxy..." current
2 August 2024
- 05:4405:44, 2 August 2024 diff hist +5,253 N In particular the high aspect ratio of dot arrays on 110 nm thick resist is confirmed by a standard liftoff process of 20 nm thick gold nanodots at sub15 nm feature size and 40 nm pitch Created page with "The smallest gold nanodot size from our A comprehensive model for sub-10 nm electron-beam patterning through the In this study, we propose a set of single-spot experiment to construct a comprehensive model of electron-beam lithography to describe the relation among the incident electrons, resist, and the development conditions such as durations and temperatures. Through the experiments, small feature can be achieved by performing a short-time development due to the high..." current
- 03:2103:21, 2 August 2024 diff hist +5,128 N The onepot procedure uses microwave heating to initiate an intramolecular 4 2cycloaddition of an alkynol segment onto a furan followed by a fragmentation aromatization and NBoc deprotection cascade Created page with "Yields range from 15 to 74%, with aromatic substituents providing better conversions. 4-Trimethylsilylated analogues undergo a 1,3-silatropic rearrangement to give the O-TMS ethers.Correlations and prediction of adsorption capacity and affinity of aromatic Massachusetts, 161 Holdsworth Way, Amherst, MA 01003, USA.Correlations capable of predicting organic compound adsorption by activated carbons (ACs) are essential to the applications of ACs as environmental adsorbents i..." current
1 August 2024
- 02:5802:58, 1 August 2024 diff hist +5,087 N At higher temperatures the genotoxicity DNA adducts and mutagenicity rapidly declined to very low levels Created page with "Different petroleum products showed a more than 100-fold range in DNA adduct formation, with severely hydrotreated base oil and bitumen fume condensates being lowest. Coal tar distillates showed ten times higher levels of DNA adduct formation than the most potent petroleum distillate. A clustered DNA adduct pattern was seen over a wide distillation range after metabolic activation with liver extracts of rat or human origin. These clusters were eluted in a region where al..." current
30 July 2024
- 09:1509:15, 30 July 2024 diff hist +4,974 N RESULTS AND DISCUSSION In the presence of both oxygen and sensitizer furalaxyl underwent rapid photochemical transformations mainly to Ndisubstituted formamide maleic anhydride and a 25Hfuranone derivative Created page with "The formation of these products was rationalized in terms of a furan endoperoxide intermediate derived from the reaction of furalaxyl with active dioxygenated species (singlet oxygen, superoxide anion or ground state oxygen). The 2(5H)-furanone exhibited a higher toxicity than the parent compound.CONCLUSION: This work reports the first data on the photosensitized oxygenation of furalaxyl with evidence of the high tendency of the pesticide to undergo photodegradation unde..." current
29 July 2024
- 08:1708:17, 29 July 2024 diff hist +5,367 N Raman results showed char of 600C deposited more pure aromatic structures the influence of temperature on aromatization was stronger than that of heating rate Created page with "declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this Effects of long-term fertilization on soil humic acid composition and structure Agricultural Sciences, Key Laboratory of Soil Environment and Plant Nutrition of The composition and structure of humic acid (HA) can be affected by fertilization, but the short-term effects are difficult to detect using traditional analysis m..." current
26 July 2024
- 05:5805:58, 26 July 2024 diff hist +5,261 N Besides the Mbius topology hexaphyrins can adopt a variety of conformations with Hckel and twisted Hckel topologies which can be interconverted under certain conditions Created page with "To determine the optimum conditions for viable Möbius topologies, the conformational preferences of [26]- and [28]hexaphyrins and the dynamic interconversion between the Möbius and Hückel topologies were investigated by density functional calculations. In the absence of meso substituents, [26]hexaphyrin prefers a planar dumbbell conformation, strongly aromatic and relatively strain free. The Möbius topology is highly improbable: the most stable tautomer is 33 kcal mo..." current
25 July 2024
- 03:0403:04, 25 July 2024 diff hist +5,620 N This system exhibited a photocytotoxicity index PI of 15 which is in marked contrast to most other RuII complexes including those designed for O2 independent mechanisms of action Created page with "© 2019 American Society for Photobiology.Decontamination of Escherichia coli O157:H7 and Salmonella enterica on blueberries using ozone and pulsed UV-light.Sciences, The Pennsylvania State Univ., Univ. Park, PA 16802, USA.Efficacy of gaseous ozone, aqueous ozone, and pulsed UV-light was evaluated for the purpose of decontaminating blueberries artificially contaminated with either Escherichia coli O157:H7 or Salmonella.<br /><br /> Blueberries were exposed to 4 different..." current
23 July 2024
- 03:2903:29, 23 July 2024 diff hist +5,347 N Oxamatobased dicopperII metallacyclophanes also emerge as potential candidates for the study of coherent electron transport through single molecules both experimentally and theoretically Created page with "The results presented herein, which are a first step in the metallosupramolecular approach to molecular spintronics, intend to attract the attention of physicists and materials scientists with a large expertice in the manipulation and measurement of single-molecule electron transport properties, as well as in the processing and addressing of molecules on different supports.Access to Disparate Soft Matter Materials by Curing with Two Colors of Light.University of Technolo..." current
19 July 2024
- 03:0703:07, 19 July 2024 diff hist +5,245 N Our results demonstrate that neurons on P3HT nanofibers showed a significantly higher total number of branches while neurons grown on P3HT microfibers had longer and thinner neurites Created page with "Such a combination strategy of topographical and photoconductive stimulation can be applied to further enhance neuronal differentiation and directed growth. These photoconductive polymeric micro/nanostructures demonstrated their great potential for neural engineering and development of novel neural regenerative devices.Effects of mixed cultures of Candida tropicalis and aromatizing yeast in alcoholic fermentation on the quality of apple vinegar.There are two steps (alcoh..." current
18 July 2024
- 02:4602:46, 18 July 2024 diff hist +5,145 N Our results demonstrate that dilbit can be effectively degraded by autochthonous microbial consortia from sites with recent exposure to dilbit contamination Created page with "[https://anotepad.com/notes/xaahwm7t 6-butyl-n-hydroxynaphthimide trifluoromethanesulfonic acid as a Catalyst in Organic Transformations] for assessing toxic dermal exposures of firefighters during suppression of structural burns.Protection Agency, Research Triangle Park, NC, USA.Firefighters wear fireproof clothing and self-contained breathing apparatus (SCBA) during rescue and fire suppression activities to protect against acute effects from heat and toxic chemicals. F..." current
11 July 2024
- 03:5903:59, 11 July 2024 diff hist +5,558 N High efficiency of this process can be achieved by the nearfield enhancement close to metallic NPs present in the polymer thin film Created page with "First evidence is given here with protected amine side groups when spin coating the copolymer over sharp gold edges as obtained from triangular metallic NPs (i.e. so-called Fischer pattern); after laser exposure at 790 nm, the photochemically deprotected amines were successfully photo-labeled and then © 2015 P. Reichenbach et al., published by De Gruyter.Chemical nature of humic substances in two typical Chinese soils (upland vs paddy soil): A comparative advanced solid..." current
9 July 2024
- 04:1104:11, 9 July 2024 diff hist +5,424 N In this study we present a facile method for synthesizing three derivatives of circumcoronene using BrnstedLewis acidmediated cyclization of vinyl ether or alkyne Created page with "Their structures were confirmed through X-ray crystallographic analysis. Bond length analysis, NMR measurement, and theoretical calculations showed that circumcoronene mostly follows Clar's bonding model and exhibits dominant local aromaticity. Its absorption and emission spectra are similar to those of the smaller hexagonal coronene due to its six-fold symmetry.Halogenated semivolatile acetonitriles as chloramination disinfection by-products in water treatment: a new fo..." current
4 July 2024
- 03:5103:51, 4 July 2024 diff hist +6,136 N The degradation of the microstructures is tracked and quantified using AFM measurements of their height Created page with "The influence of the writing parameters as well as the degradation conditions is investigated, unambiguously evidencing effective visible light degradation in aqueous environments. Finally, [https://canvas.instructure.com/eportfolios/2652858/Home/_The_impact_of_chloride_on_the_decomposition_of_shortchain_carboxylic_acid_intermediates_from_aromatics_degradation_has_often_been_overlooked Learn more] of the photodegradable resist system is demonstrated by incorporating it i..." current
1 July 2024
- 03:4203:42, 1 July 2024 diff hist +5,820 N Four of the eight products showed low to moderate growth inhibition against several Grampositive and negative bacterial strains and against the yeasts Candida maltosa and Candida albicans Created page with "The antibacterial and antifungal activities were determined by an agar disc diffusion test and a modified method according to the EUCAST discussion document E.Dis 7 [Rodríguez-Tudela et al. (2003) Clin. Microbiol. Infect. 9, i-viii] for the evaluation of MIC (minimal inhibitory concentration).<br /><br /> Differences in cytotoxicity against the human urinary bladder carcinoma cell line 5637 are discussed.Disruption of a global regulatory gene to enhance central carbon f..." current
21 June 2024
- 08:4908:49, 21 June 2024 diff hist +5,395 N Each CRE has the same sign and essentially the same magnitude as the corresponding cyclic conjugation energy CCE defined by Bosanac and Gutman Created page with "Such CREs were found to play a crucial role in associating the energetic criteria for determining the degree of aromaticity with the magnetic ones. We can now interpret both energetic and magnetic criteria of aromaticity consistently in terms of CREs. Ring-current diamagnetism proved to be the tendency of a cyclic pi-system to retain aromatic stabilization energy (ASE) at Aromaticity Reversal in the Lowest Excited Triplet State of Archetypical Möbius Systems, Yonsei Uni..." current
17 June 2024
- 04:4104:41, 17 June 2024 diff hist +5,422 N The novelty arises from the simplicity of the master and photoresistfree microstructuring and the higher stiffness of SiOxCOP stamps prevents the deformation during pressing Created page with "Finally, an example μCP is given to transfer titania precursor gel and produce TiO2 micropatterns on flexible polymer substrates. The SiOx/COP stamps and the μCP of TiO2 provide simple and cost-effective patterning techniques, which should contribute to the future design and creation of flexible devices.Guided Electrokinetic Assembly of Polystyrene Microbeads onto Photopatterned Irvine, 5200 Engineering Hall, Irvine, California 92627, United States200 Engineering Hall,..." current
14 June 2024
- 02:3502:35, 14 June 2024 diff hist +5,378 N Herein we consider a series of symmetrically substituted conjugated rings with potential Baird aromaticity in the lowest excited triplet and singlet states Created page with "Our computational results allow us to establish general guidelines for the rational design of molecules with excited state Hückel/Baird aromaticity in pro-aromatic quinoidal compounds. We found two main strategies to promote high Baird aromatic character: 1) anionic and small conjugated rings with electron donating groups as substituents and small exocyclic groups with electron withdrawing substituents, or 2) electron deficient conjugated rings with exocyclic electr..." current
12 June 2024
- 04:4104:41, 12 June 2024 diff hist +5,435 N Importantly the presented technique does not impose any restrictions regarding the shape and length of the metallic pattern Created page with "Plasmonic interactions have been probed using both Stokes and anti-Stokes types of emitters that served as photoluminescence probes. For [https://pastelink.net/33xjj0qd Seebio Photoinitiator] , we observed a pronounced increase of the photoluminescence intensity for emitters deposited on silver patterns. By studying the absorption and emission dynamics, we identified the mechanisms responsible for emission enhancement and the position of the plasmonic resonance.Stochasti..." current
7 June 2024
- 03:5503:55, 7 June 2024 diff hist +5,432 N Heavy metals together with their associated water molecules decreased the sorption of target chemicals on BC700 via porefilling or poremouthcovering Created page with "Inhibition of heavy metals for 4-nitro-1-naphthol was found to be the weakest due to the bridge effects of heavy metals between 4-nitro-1-naphtol and BC700. The higher polarizability of Ag+ led to the increase of its sorption on biochars in the presence of organic aromatic pollutants. The results of the present study shed light on the sorption mechanisms of bi-solute systems and enable us to select suitable biochar Further studies of the Enhanced Structural Carborane Eff..." current
30 May 2024
- 03:3203:32, 30 May 2024 diff hist +5,220 N However little quantitative data exist on the migration and attenuation of ARGs in estuary ecosystem which is central to predicting their fate after release into marine environment Created page with "Moreover, [https://skovbjerglaug.livejournal.com/profile Seebio Photosensitive Acid Generator] of multiple chemical contaminants and water quality constituents should be understood to amplify and attenuate antibiotic resistance levels. To determine the prevalence and examine the fate of sulfonamide ARGs (sul-ARGs) in two estuaries under different effects of anthropogenic activities, we analyzed the sul-ARGs (sul1, sul2, and sul3), class 1 integrons (int1), and bacterial..." current
28 May 2024
- 03:3603:36, 28 May 2024 diff hist +5,870 N The textbook concept of shielding cone is one of the characteristic properties for planar aromatic species which explains the nuclear shielding of neighbor molecules located above and below the molecular plane Created page with "Here, we explore its resemblance in spherical aromatic fullerenes, where particularly for C606-, it explains the record for the highest shielding observed via 3He-NMR for the induced shielding cone was observed for the latter with its long-range shielding character. In contrast to planar aromatics which give rise to a shielding cone property only for a perpendicularly oriented field, it was found that the shielding cone in spherical aromatic fullerenes occurs to any orie..." current
24 May 2024
- 03:4003:40, 24 May 2024 diff hist +5,621 N The information for strains and structural specific barriers appears to be contained exclusively in the folding of the pathological isoform PrPSc Created page with "Many recent studies determined that de novo prion strains could be generated in vitro from the structural conversion of recombinant (rec) prion protein (PrP) into amyloidal structures. Our aim was to elucidate the conformational diversity of pathological recPrP amyloids and their biological activities, as well as to gain novel insights in characterizing molecular events involved in mammalian prion conversion and propagation. To this end we generated infectious materials..." current
23 May 2024
- 03:5503:55, 23 May 2024 diff hist +5,601 N The xylenes underwent three processes of photoisomerization photodecomposition and photooxidation to produce intermediates of aromatics alkanes and carbonyls Created page with "Among them, the photo-isomerization products showed the highest concentration percentage (e.g., ≥50% in o-xylene system), confirming that photo-isomerization reaction was the dominated photodegradation process of xylenes. Moreover, these isomerized products not only contributed about 97% and 91% to the formation potential of O3 (OFP) and secondary organic aerosols (SOAFP), but also displayed obvious non-carcinogenic risk, although one of photodecomposition product-benz..." current
22 May 2024
- 03:3603:36, 22 May 2024 diff hist +5,479 N Coradiolysis of benzene with nitrite generates NO2 in addition to the hydroxycyclohexadienyl radical Created page with "[https://sensible-carnation-h1pfjj.mystrikingly.com/blog/the-newly-available-meso-tetraarylazuliporphyrins-13-similarly-afforded-the Seebio Photoinitiator] interact with one another (product: nitrobenzene via nitro-hydroxycyclohexadienes) but the *NO2 radical is also capable of abstracting cyclohexadienylic hydrogens. This reaction leads to the formation of 2- and 4-nitrophenol and to further nitrated products that were not identified. These are suggested to be formed in..." current
20 May 2024
- 02:1002:10, 20 May 2024 diff hist +5,229 N The aromaticityantiaromaticity of substituted cyclopentadienyl derivatives has been measured using energetic magnetic and structural criteria to take into account the multidimensional character of aromaticity Created page with "Furthermore, the Euclidean distance values (d(j)) for all compounds have been estimated using the neural network developed previously. It has been demonstrated that the d(j) as a scale of aromaticity overcomes the particular limitations of the ASE, Lambda, NICS and HOMA indices to describe the changes in the aromaticity of cyclopentadiene ring due to substituent effects. Additionally, it is shown that neural networks are useful tools for establishing structure-property r..." current
16 May 2024
- 04:0804:08, 16 May 2024 diff hist +5,531 N With the possible exception of shallow water bodies containing low dissolved organic carbon we predict ACE to be a refractory compound in environmental waters which agrees well with many literature reports Created page with "We used two methods to measure the photoreactivity parameters of ACE, of which one is based on the monitoring of the time evolution of ACE alone and the other is based on the monitoring of both ACE and a reference compound (hereafter, they are referred to as substrate-only and substrate + reference method, respectively). The substrate + reference method can be time-saving, but it is potentially prone to interferences. In this work, ibuprofen and atraz..." current
10 May 2024
- 04:0604:06, 10 May 2024 diff hist +5,594 N Significant challenges arise with shrinking feature sizes such as etching with thin masks Created page with "Traditionally this has been addressed with hard masks and consequently additional costly steps. Here we present a pathway to high selectivity soft mask pattern transfer using cryogenic plasma etching towards low-cost high throughput sub-10 nm nanofabrication. selectivity inductively coupled plasma etching of silicon. Selectivity was maximized on large features (400 nm-1 μm) with a focus on minimizing photoresist etch rates. An overall anisotropic profile with selectivit..." current
8 May 2024
- 03:4103:41, 8 May 2024 diff hist +5,687 N Almost all the main ringcleavage pathways for aromatic compounds are found in C Created page with "necator: the beta-ketoadipate pathway, with its catechol, chlorocatechol, methylcatechol and protocatechuate ortho ring-cleavage branches; the (methyl)catechol meta ring-cleavage pathway; the gentisate pathway; the homogentisate pathway; the 2,3-dihydroxyphenylpropionate pathway; the (chloro)hydroxyquinol pathway; the (amino)hydroquinone pathway; the phenylacetyl-CoA pathway; the 2-aminobenzoyl-CoA pathway; the benzoyl-CoA pathway and the 3-hydroxyanthranilate pathway. A..." current
7 May 2024
- 03:2503:25, 7 May 2024 diff hist +5,516 N The major part of mutagenicity 5565 was present in the fraction of polar aromatics followed by polar neutrals and the acetone subfraction of cyclohexane solubles approximately 10 each summarizing the results obtained with S Created page with "typhimurium TA 98, TA 98NR, YG 1021, YG 1024, TA 100, YG 1026, and YG 1029 with and without addition of S9. [https://diigo.com/0v86j1 Characterization and Spectroscopic Analysis of 6-butyl-n-hydroxynaphthimide trifluoromethanesulfonic acid] modified tester strains, either deficient in nitroreductase (TA 98NR) or overproducing nitroreductase (YG 1021, 1026) or O-acetyl-transferase (YG 1024, 1026), indicated a major contribution of nitroarenes to soil mutagenicity. With re..." current
30 April 2024
- 03:2203:22, 30 April 2024 diff hist +5,318 N We then found that the degree of macrocyclic aromaticity is very sensitive to the way of oligomerization Created page with "In general, it is markedly suppressed by linkage or substitution at meso positions but is fairly insensitive to direct edge-to-edge fusion. These predictions are consistent with observed chemical shifts of protons attached to the porphyrin macrocycles. Antiaromatic circuits are created in doubly- and triply-linked porphyrin oligomers. These circuits must be the origin of paramagnetic currents induced around the naphthalene-like junction zones in triply-linked oligomers...." current
29 April 2024
- 03:3403:34, 29 April 2024 diff hist +22 m Ambient temperature ligation of diene functional polymer and peptide strands onto cellulose via photochemical and thermal protocols No edit summary current
25 April 2024
- 03:5003:50, 25 April 2024 diff hist +5,224 N For a special HTI molecule namely an omegaamino acid the ZE isomerization process occurs on a timescale of 30 ps Created page with "In the course of the reaction fast processes on the 1-10 ps timescale are observed which point to motions of the molecule on the potential-energy surface of the excited state. The combination of transient absorption experiments in the visible spectral range with time-resolved fluorescence and infrared measurements reveal a photochemical pathway with three intermediate states. Together with a theoretical modelling procedure the experiments point to a sequential reaction s..." current
24 April 2024
- 04:0704:07, 24 April 2024 diff hist +5,780 N Plausibility arguments for the conditions favouring a quantum mechanism of signal propagation along a microtubule are provided Created page with "Overall, we find that coherent energy transfer in tubulin and microtubules is © 2014 The Author(s) Published by the Royal Society. All rights reserved.Characterizations of volatile organic compounds during high ozone episodes in Atmospheric Physics, Nanjing University of Information Science & Technology, Air samples were collected in Beijing from June through August 2008, and concentrations of volatile organic compounds (VOCs) in those samples are here discussed. Th..." current
22 April 2024
- 05:5005:50, 22 April 2024 diff hist +5,350 N However developing artificial materials in which molecularlevel motions could be amplified to behave macroscopically is still challenging Created page with "Herein, we present a class of mechanically interlocked networks (MINs) carrying densely rotaxanated backbones as a model system to understand macroscopic mechanical properties stemmed from the integration and amplification of intramolecular motion of the embedded [2]rotaxane motifs. On the one hand, the motion of mechanical bonds introduces the original dangling chains into the network, and the synergy of numerous such microscopic motions leads to an expansion of entire..." current
19 April 2024
- 04:3904:39, 19 April 2024 diff hist +5,463 N The resulting longrange ordered fibrous nanodrugs show improved photophysical capabilities for fluorescence imaging and photothermal conversion and significantly promote the proliferation and differentiation of antitumor immune cells Created page with "Hence, the integration of rapid photothermal therapy and moderate immunomodulation for inhibiting tumor growth and eliminating tumor metastasis is promising. The utilization of clinically approved molecules to construct nanodrugs administered via localized injection amplifies the complementary photothermal immunotherapeutic effects of the components, creating opportunities for clinical translation as a treatment for pancreatic cancer.Microbial degradation of phthalates:..." current
- 03:2803:28, 19 April 2024 diff hist +4,949 N This study assessed the influence of gasoline fuels with varying levels of aromatics and ethanol on the primary emissions and secondary aerosol formation from a flexible fuel vehicle equipped with a port fuel injection engine Created page with "The vehicle was exercised over the LA92 and US06 driving cycles using a chassis dynamometer. Secondary aerosol formation potential was measured using a fast oxidation flow reactor. Results showed that the high aromatics fuels led to higher gaseous regulated emissions, as well as particulate matter (PM), black carbon, and total and solid particle number. The high ethanol content fuel (E78) resulted in reductions for the gaseous regulated pollutants and particulate emissio..." current